Because of the distinctive colors of the precipitates formed, various cations have been proposed for the qualitative detection of the ferrocyanide ion. Since interference frequently occurs, some care is usually necessary. As an illustration, the following condensed procedure serves for the detection of the ferrocyanide ion in the presence of ferricyanide
It is generally agreed that the ferrocyanide ion is of a low order of oral toxicity, even in relatively large dosage. Kobert states that potassium ferrocyanide in alkaline solution is nontoxic. In Precis de Toxicologie it likewise is asserted that this salt is nonpoisonous and that it is useful as a diuretic. There is recorded a case of ingestion
Alkali metal ferrocyanides and their easily obtainable derivatives such as ferricyanides, nitroprussides, and hydroferrocyanic acid have found application in a wide variety of fields during the two centuries that they have been known. Through continued research new uses are being uncovered with increasing frequency.
Most of these applications
Hydroferrocyanic acid is most conveniently prepared by the treatment of an alkali metal ferrocyanide with a strong mineral acid. A typical preparation would involve the treatment of a saturated aqueous solution of potassium ferrocyanide with concentrated hydrochloric acid. The acid separates as a crystalline solid that may be purified further
In the Cyanide Destruction by Hypochlorite reaction, the pH has a strong inverse effect on the ORP. Thus, wastewater treatment facilities must closely control the pH to achieve consistent ORP control, especially if they use hypochlorite as the oxidizing agent. Adding hypochlorite raises the pH, which, if unchecked, lowers the ORP. calling for additional
The continuity of operation of a lime sludge kiln requires strict maintenance control. The rotary kiln is among the largest type of moving machines made and is subjected to extreme temperatures, power failures, atmospheric conditions, varying loads, and other operating conditions
Precipitated calcium carbonate, commonly called lime sludge or lime mud, is produced when sulphate green liquor is causticized with lime. For many years this lime sludge was considered a waste product and was dumped into rivers or waste ponds, or used for fill around the plants. Large quantities of new lime were purchased from commercial
Since acidity of the ore causes decomposition of the cyanide, an obvious method of reducing the loss is to add alkali in some form. Before doing this, the free sulphuric acid and soluble salts may be removed by leaching with water, and then a solution of caustic soda or lime is run on to the ore, and after standing for some time is drained off and
The cyanide is usually dissolved in a little water before being added to the stock solution, as the amount of KCy present is more easily determined in a strong solution than in any other form. A special dissolving vat of small size is often provided and is placed at a higher level than the large vats used for the storage of the stock solution. High
Gold Monochloride or Aurous Gold Chloride ?AuCl? is a salt is prepared by heating the trichloride to 185° in air for twelve hours. It is non-volatile and unaltered at ordinary temperatures and pressure by dry air, even when exposed to light, but begins to decompose at temperatures
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