Pyrometallurgy: Roasting, Smelting, Refining & Electrowinning

Pyrometallurgy: Roasting, Smelting, Refining & Electrowinning

  • To participate in the 911Metallurgist Forums, be sure to JOINLOGIN
  • Use Add New Topic to ask a New Question/Discussion about Pyrometallurgy and Electrometallurgy.
  • OR Select a Topic that Interests you.
  • Use Add Reply = to Reply/Participate in a Topic/Discussion (most frequent).
    Using Add Reply allows you to Attach Images or PDF files and provide a more complete input.
  • Use Add Comment = to comment on someone else’s Reply in an already active Topic/Discussion.

zadra cell (3 replies and 4 comments)

m
mohammed_tawfik
6 years ago
mohammed_tawfik 6 years ago

And could i use a zadra cells for one tone of active carbon ?

Which pregnant solution does it work on ?

does it work  after the active carbon or don't  require active carbon stage ?

What is the recovery rate of the cell ?

our operation include vat leaching and carbon column we used to burn carbon to retrieve gold, now we want to use zadra cell , so  from what i get on line it work on pregnant solution, which one?

the cyanide solution before the carbon or after it?  and what about its recovery rate? how much  could i collect using it? is it suitable for one ton carbon?

Thank you

 

V
vivekr31
6 years ago
vivekr31 6 years ago

Hi Mohammed,

yes. You get Zadra systems for 1 tonne. The adsorbed carbon needs to be eluted through the elution column with 4% caustic and 2% cyanide solution at around 130 deg C. The gold bearing strip solution is called as pregnant solution which then has to go through the EW cells and gold gets deposited in Cathode (Stainless steel wool). The stripped carbon is regenerated through Electric Kiln and sent back to Adsorption circuit.

m
mohammed_tawfik
6 years ago

What about its recovery rate !
Does it have a good yield
Its better than the electrowinning cell ?

V
vivekr31
6 years ago

Electrowinning follows Elution.You need EW to recover gold from eluant solution. I dont understand what you mean by recovery. But the complete gold in carbon can be desorbed (recovered) in 16- 24 hrs.

m
mohammed_tawfik
6 years ago

if i established a zadra cell is it enough to collect gold ?
it come after the carbon column ? or don't require active carbon step ?

using vat leaching with sodium cyanide the solution resulting from that step i put it directly to zadra cell or had to use active carbon ?
could you please tell me the operating procedure of the cell ?

V
vivekr31
6 years ago
vivekr31 6 years ago
1 like by David

The zadra operates in fairly elevated temperature and hence you need less volume to handle. This means you got to place it after carbon circuit which adsorbs gold from cyanide solution and you then again treat this carbon with cyanide and caustic to desorb from carbon (less volume to handle). Enclosed image may be little help.

zadra
https://www.911metallurgist.com/wp-content/uploads/2018/02/Zadra.png
m
mohammed_tawfik
6 years ago

so its like electrowinning cell but smaller; better to use the electrowinning cell.

could you help me with the lead acid method for determination of gold concentration in gold cyanide solution ?

m
mohammed_tawfik
6 years ago
mohammed_tawfik 6 years ago

Procedures. Inorganic Concentration: Lead - Acid
Reagents
C Granulated lead: + 10 mesh - (screened test lead may be used)
C Concentrated HCl
C Lead Foil (7.5 cm x 7.5 cm)
C Ag for inquartation (AgNO3, solid inquart, etc.)
Procedure
1) Measure an appropriate aliquat of sample (typically 300 ml or 150 ml) of cyanide
solution into a 600 ml beaker.
2) Add 1 ml AgN03 solution (6g/l) and mix well.
3) Heat to just below boiling point. Add about 1/2 tsp (9 to 16 g) granulated lead.
4) Add 10 ml concentrated HC1 (CAUTION), cover with watch glass, and boil
strongly for 10 to 15 minutes.
5) Cool solution, and carefully decant so as not to lose any lead.
6) Wash lead twice with deionized water by decantation and dry on a hotplate.
7) When dry, transfer the lead into a piece of prefolded lead foil. Wrap carefully, and
cupel. Part dore , anneal, and weigh gold bead.
Calculation
Au in solution (oz/ton) = Bead weight (mg) * 29.166/sample volume (ml)
C Notes (Battle Mountain Gold)
Method has been compared to several others we have used, in particular the
Copper Sulfate Collection method. With most solutions, assay results showed
no significant bias. With foul solutions, the amount of HC1 added may have to
be increased and reaction times may have to be increased as well. This also
holds for high Au concentrations, though we have not made any detailed
studies regarding this cutoff concentration.

that is the method i mean

Please join and login to participate and leave a comment.