Laboratory Procedures

Manganese in Mineral Chromite, Ferrochrome Slags, and Ferrochrome

Manganese commonly occurs in mineral chromite as an impurity, and the amount can range from trace quantities to a few percent. In ferrochrome smelting operations, the manganese should find its way into the slag rather than the metal. Data from these analyses have most often been used to trace the partitioning of the manganese through … Read more

Gravimetric Silica in Mineral Chromite and Ferrochrome Slags

Silica is present in chromite ores as a basic silicate. In characterization and beneficiation studies performed on chromites at this Center, the chromium-silica ratio determines the purity of the gangue material being analyzed. Accurate characterization of the original ore material and the further feasibility of smelting to ferrochrome are identified by using this ratio. The … Read more

Calcium in Mineral Chromite and Ferrochrome Slags

Calcium is rarely found in chromite ores in amounts greater than a few tenths of a percent, and calcium analysis is rarely requested on ore samples. Calcium compounds are, however, used as slag conditioners for ferrochrome smelting. Most of the chromite-related samples received for calcium analysis at this Center have been slag samples. The data … Read more

Aluminium and Magnesium in Mineral Chromite and Ferrochrome Slags

Aluminum and magnesium occur as gangue components in chromite ores and ferrochrome slags. At this Center, ores from many different sites and of many varieties are examined for commercial feasibility. The beneficiation of these ores is a continuing activity that produces most of the samples that are analyzed with this method. Data from this method … Read more

Metallic Iron in Ferrochrome Slags

It would truly be unusual to find a sample of mineral chromite with metallic iron in it. However, (his Center has handled many samples of prereduced smelter charges with several percent of metallic iron and ferrochrome slags with measurable quantities of metallic iron. Therefore, this method finds its use in the later stages of mineral … Read more

Ferrous Iron in Mineral Chromite and Ferrochrome Slags

The determination of ferrous iron in mineral chromites and other chromite-bearing samples is limited by the difficult solubility of the chromite lattice. Reaction of the ferrous iron immediately upon release from the crystal seems to be the preferred way of measurement. Attempts to dissolve chromite by other methods depend on strong oxidizing agents that leave … Read more

Total Iron in Mineral Chromite and Ferrochrome Slags

Iron is the second major element in chromite. In smelting operations where ferrochrome is the product, a specific range in the chromium-to-iron ratio is desired. Where pure metallic chromium is the product, the iron concentration is not as important. In both cases, it is important to have a good value for the chromium-to-iron ratio. A … Read more

Acid-Soluble or “Metallic” Chromium in Ferrochrome Slags

At this Center, results from this method have been used almost exclusively as data for the calculation of the total degree of reduction in a smelter batch, rather than as an indicator for the metallization of chromium. When a charge of chromite material is smelted or prereduced, the crystal structure is changed, and once the … Read more

Total Chromium in Mineral Chromite and Ferrochrome Slags

The total chromium content in mineral chromite and ferrochrome slags can range from a fraction of a percent in the slags to greater than 30 pct in the ore concentrates. Because of this variation and because of the difficulty in dissolving chromite-containing samples, the method of choice at this Center has been fusion with sodium … Read more

Methods for the Analysis of Mineral Chromites and Ferrochrome Slag

This report describes the elemental characterization of chromite and related materials at the Bureau of Mines, Albany Research Center. Analytical methods for determining the major constituents, representing extensive experience, refinement, and development, are described and fully annotated. This presentation should allow other laboratories to use these methods and obtain comparable results with a minimum of … Read more