Pyrometallurgy: Roasting, Smelting, Refining & Electrowinning

Pyrometallurgy: Roasting, Smelting, Refining & Electrowinning

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Help identifying tin bronze anomaly in copper cent (1 reply)

S
Coins7112
1 year ago
Coins7112 1 year ago

Need assistance in identifying a cause of a tin bronze occurring in 1910/1911 Lincoln wheat cent. Flake like features on a small run of Lincoln wheat cents have been identified. SEM/EDX reading shows flakes reading higher than normal SN and ZN. Copper cent should contain 95% CU and 5% ZN,SN. Flake readings are 86% CU 11%SN and 2.5%Zn, within these flakes there are multiple areas containing 64% CU and 33% SN. This flake becomes tin bronze and resists tarnish. I am trying to understand how this can occur. Any help would be greatly appreciated.

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https://www.911metallurgist.com/wp-content/uploads/2023/02/DD88A89E-66CD-40A7-8EEC-5B296E5A1D54.jpeg
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Mike
1 year ago
Mike 1 year ago

The most likely reason would be poor control during the smelting proces allowing for poor mixing in the cupela or a batch of material with the wrong percentages in the mix.

Another possibility would be leaving the coin(s) out near an ammonia source or fumes as ammonia is a lixivent for copper.

 

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