Assaying Iridium Determination Method

Assaying Iridium Determination Method

Occurs in nature alloyed with osmium as osmiridium or iridosmine, which is “ rather abundant in the auriferous beach sands of Northern California” (Dana). It occurs in bright metallic scales, which do not alloy with lead, and are insoluble in aqua regia. Iridium also occurs in most platinum ores, and forms as much as two per cent, of some commercial platinum. In chemical properties it resembles platinum, but the ammonic irido-chloride has a dark red colour, and on ignition leaves metallic iridium, which does not dissolve in aqua regia diluted with four or five times its volume of water and heated to a temperature of 40° or 50° C.

The other metals of the platinum group are Palladium, Rhodium, Osmium, and Ruthenium. They differ from gold, platinum, and iridium by the insolubility of their sulphides in a solution of sodium sulphide. Palladium is distinguished by the insolubility of its iodide ; and Osmium by the volatility of its oxide on boiling with nitric acid.